BRAGA, A.N.S.; http://lattes.cnpq.br/2429557575387821; BRAGA, Aluska do Nascimento Simões.
Resumen:
Mullite is a synthetic material that has received particular attention due to their
chemical, physical and mechanical properties, which are correlated with the
synthesis method used. The sol-gel method stands out compared to the other
chemical methods due to the possibility of obtaining materials with high purity
and low temperatures for synthesis. Therefore, this study aims to analyze the
influence of the solvent to obtain mullite via different sol-gel routes: Pechini
route, route by route by slow gelation and rapid gelation. Studied for each route
was examined the influence of the solvents water, ethyl alcohol, isopropyl
alcohol and tetrahydrofuran (THF), to obtain mullite. The samples were
characterized by X-ray diffraction (XRD), thermal analysis (TG and DTA),
nitrogen adsorption (BET), scanning electron microscopy (SEM) and
transmission electron microscopy (TEM). The results showed the influence of
different routes and solvents in obtaining the mullite. By the Pechini Route
mullite was formed when it used only ethanol as a solvent. In the slow and fast
gelling all solvents studied crystallized mullite depending on the control of other
process variables, such as solvent used, the solution concentration,
temperature, etc. Comparatively, the Pechini Route mullite obtained with lower
crystallinity than all other routes, has the largest surface area and a more
porous morphology. In the slow gelation mullite was synthesized in almost all
synthesis conditions and all solvents, however, the use of alcohols as solvent
gave obtaining the most crystalline samples with high reactivity, having the
smaller surface areas, with a morphology formed by aggregates and individual
particles. In the fast gelation of the solution at low concentration with the use of
alcohols as solvent, was indicated condition. However, this route showed more
heterogeneities having lower crystallinity, and thus superficias larger areas, for
the slow gelation morphology being formed by large aggregates and
considerable amount of glassy phase.